全文获取类型
收费全文 | 63380篇 |
免费 | 5689篇 |
国内免费 | 2878篇 |
专业分类
电工技术 | 3548篇 |
技术理论 | 2篇 |
综合类 | 4150篇 |
化学工业 | 10532篇 |
金属工艺 | 3711篇 |
机械仪表 | 4079篇 |
建筑科学 | 4697篇 |
矿业工程 | 2141篇 |
能源动力 | 1696篇 |
轻工业 | 4044篇 |
水利工程 | 1081篇 |
石油天然气 | 3902篇 |
武器工业 | 529篇 |
无线电 | 7693篇 |
一般工业技术 | 7716篇 |
冶金工业 | 2978篇 |
原子能技术 | 635篇 |
自动化技术 | 8813篇 |
出版年
2024年 | 177篇 |
2023年 | 1097篇 |
2022年 | 1570篇 |
2021年 | 2526篇 |
2020年 | 1970篇 |
2019年 | 1749篇 |
2018年 | 1914篇 |
2017年 | 2115篇 |
2016年 | 1916篇 |
2015年 | 2490篇 |
2014年 | 3038篇 |
2013年 | 3650篇 |
2012年 | 4098篇 |
2011年 | 4483篇 |
2010年 | 3724篇 |
2009年 | 3553篇 |
2008年 | 3431篇 |
2007年 | 3320篇 |
2006年 | 3687篇 |
2005年 | 3053篇 |
2004年 | 2131篇 |
2003年 | 1824篇 |
2002年 | 1593篇 |
2001年 | 1451篇 |
2000年 | 1565篇 |
1999年 | 1705篇 |
1998年 | 1506篇 |
1997年 | 1270篇 |
1996年 | 1133篇 |
1995年 | 945篇 |
1994年 | 828篇 |
1993年 | 564篇 |
1992年 | 424篇 |
1991年 | 364篇 |
1990年 | 252篇 |
1989年 | 212篇 |
1988年 | 179篇 |
1987年 | 111篇 |
1986年 | 93篇 |
1985年 | 57篇 |
1984年 | 28篇 |
1983年 | 18篇 |
1982年 | 28篇 |
1981年 | 16篇 |
1980年 | 21篇 |
1979年 | 10篇 |
1978年 | 7篇 |
1977年 | 5篇 |
1976年 | 14篇 |
1975年 | 9篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
71.
Yanlong Shi Xiaojuan Feng Haiyu Guan Jiahua Zhang Zhongai Hu 《International Journal of Hydrogen Energy》2021,46(12):8557-8566
Constructing high-efficient and nonprecious electrocatalysts is of primary importance for improving the efficiency of water splitting. Herein, a novel sunflower plate-like NiFe2O4/CoNi–S nanosheet heterostructure was fabricated via facile hydrothermal and electrodeposition methods. The as-fabricated NiFe2O4/CoNi–S heterostructure array exhibits remarkable bifunctional catalytic activity and stability toward oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) in alkaline media. It presents a small overpotential of 219 mV and 149 mV for OER and HER, respectively, to produce a current density of 10 mA cm?2. More significantly, when the obtained electrodes are used as both the cathode and anode in an electrolyzer, a voltage of 1.57 V is gained at 10 mA cm?2, with superior stability for 72 h. Such outstanding properties are ascribed to: the 3D porous network structure, which exposes more active sites and accelerates mass transfer and gas bubble emission; the high conductivity of CoNi–S, which provides faster charge transport and thus promotes the electrocatalytic reaction of the composites; and the effective interface engineering between NiFe2O4 (excellent performance for OER) and CoNi–S (high activity for HER), which leads to a shorter transport pathway and thus expedites electron transfer. This work provides a new strategy for designing efficient and inexpensive electrocatalysts for water splitting. 相似文献
72.
Tingen Zhu Wenping Li Qiqing Wang Yanbo Hu Kaifang Fan Jiafa Du 《Mine Water and the Environment》2020,39(1):57-67
A method to calculate the height of a water-conducting fractured zone (HWCFZ) was developed based on the plate and shell theory, and the development of the HWCFZ in bedrock and Q2l loess strata is discussed in detail. First, the subsidence-deflection curve equation of the overlying stratum is theoretically derived, and then the ultimate deflection and free space height of rock strata are calculated. Moreover, the strata tensile strain is calculated by using integral calculus. In addition, the failure state of the rock is analyzed by comparing the theoretically calculated tensile strain with the experimentally measured yield tensile strain, allowing one to attain the maximum value of HWCFZ. This approach was tested at the Jinjitan coal mine; the theoretically predicted, experimentally measured, and numerically computed maximum HWCFZ values were 189.5, 187.3, and 188.5 m, respectively, demonstrating the accuracy of the proposed method. These results are highly significant for safe and environment-friendly coal mining in northwest Shaanxi, China. 相似文献
73.
Design and Fabrication of Concentration‐Gradient Generators with Two and Three Inlets in Microfluidic Chips 下载免费PDF全文
A simple and low‐cost method for designing and fabricating concentration‐gradient generators with two and three inlets is proposed which can generate different concentration gradients at varying flow velocities. The microchannel structure was designed in S‐shape and left‐right symmetry. The concentration‐gradient generator was simulated based on the finite element method. The microchannels were processed on a computer numerical control (CNC) engraving and milling machine on poly(methylmethacrylate) substrate, and then two concentration‐gradient generators were fabricated by hot bonding technology. The results of experiment and simulation were compared to prove the feasibility of the method. Flow velocity was an important factor for generating different concentration gradients. The concentration‐gradient profiles of the generators with two and three inlets present approximately linear and quadratic curves. 相似文献
75.
通过黑岱沟露天煤矿的工程试验总结了工程水压爆破技术(水土复合填塞炮孔)的原理及在露天煤矿爆破施工中的应用效果。在露天煤矿爆破施工中采用工程水压爆破技术,可以提高煤层爆破的大块率,降低单位立方岩石耗药量,降低爆破气体的温度,同时可以降低煤层爆破失火率、粉尘排放量,有效地控制爆破飞石。 相似文献
76.
77.
Yifeng Xu Bingkun Hu Jining Liu Kai Tao Ranran Wang Yang Ren Xiaofeng Zhao Jijin Xu Xuefeng Song 《Journal of the American Ceramic Society》2020,103(2):1281-1292
Microcystins (MCs) is a harmful toxin generated by blue-green algae in water, which has seriously threatened the ecological safety of water and human body. It is urgent to develop new catalysts and techniques for the degradation of MCs. A feasible electrostatic self-assembly method was carried out to synthesize BiVO4/g-C3N4 heterojunction photocatalyst with highly efficient photocatalytic ability, where BiVO4 nanoplates with exposed {010} facets anchored to the g-C3N4 ultrathin nanosheets. The morphology and microstructure of the heterojunction photocatalysts were identified by XRD, SEM, TEM, XPS, and BET. The g-C3N4 nanosheets have huge surface area over 200 m2/g and abundant mesoporous ranging from 2-20 nm, which provides tremendous contact area for BiVO4 nanoplates. Meanwhile, the introduction of BiVO4 led to red-shift of the absorption spectrum of photocatalyst, which was characterized by UV-vis diffuse reflection spectroscopy (DRS). Compared with pure BiVO4 and g-C3N4, the BiVO4/g-C3N4 heterojunction shows a drastically enhanced photocatalytic activity in degradation of microcystin-LR (MC-LR) in water. The MC-LR could be removed within 15 minutes under the optimal ratio of BiVO4/g-C3N4. The outstanding performance of the photocatalyst is attributed to synergetic effect of interface Z-scheme heterojunction and high active facets {010} of BiVO4 nanoplates, which provides an efficient transfer pathway to separate photoinduced carriers meanwhile endows the photocatalysts with strong redox ability. 相似文献
78.
The in-situ fabrication of an electron-blocking layer between the Ba-containing anode and the ceria-based electrolyte is an effective approach in suppressing the internal electronic leakage in ceria-based solid oxide fuel cell (SOFC). To improve the thickness of the electron-blocking layer and to research the effect of the layer thickness on the improvement of SOFC, a Ba-containing compound (0.6NiO-0.4BaZr0.1Ce0.7Y0.2O3-δ) modified by Y stabilized zirconia (YSZ) was employed as a composite anode in this research. SEM analyses demonstrated that the thickness of the interlayer can be simply controlled by regulating the proportion of YSZ at anode. The in-situ formed interlayer in the cell with the anode modified by 20?mol% YSZ possesses a thickness of 0.9?µm which is more suitable for the cell achieving an enhanced performance. 相似文献
79.
采用自保护药芯焊丝明弧堆焊技术制备五组不同钨含量的Fe-Cr-C-B-W合金. 借助金相显微镜、扫描电子显微镜、X射线衍射仪、洛氏硬度计和磨损试验机分析堆焊合金的组织及性能. 结果表明,合金的显微组织由马氏体、残余奥氏体、M7(C,B)3,M3(C,B),Fe3W3C和WC组成. 大部分钨元素被迁移到晶界生成了比WC稳定性更好的Fe3W3C缺碳复合相,堆焊层中没有典型的初生WC硬质相颗粒生成. 随着钨添加量的增多,共晶硬质相M7(C,B)3,M3(C,B)和Fe3W3C随之增多,间距减小,呈连续网状均匀分布. 当钨的添加量为12%时,堆焊层的耐磨性达到最佳. 相似文献
80.
Wenyun Yang Qiwei Hu Guanyi Qiao Liang Zha Shunquan Liu Jingzhi Han Honglin Du Yan Zhang Yingchang Yang Changsheng Wang 《中国稀土学报(英文版)》2019,37(10):1102-1107
In this work, we report the tuning effect of the Si substitution on the magnetic and high frequency electromagnetic properties of R2Fe17 compounds and their paraffin composites. It is found that the introduction of Si can remarkably improve the magnetic and electromagnetic properties of the R2Fe17 compounds, making the R2Fe17–xSix-paraffin composites excellent microwave absorption materials (MAMs). By introducing the Si element, their saturation magnetizations decrease slightly, while much higher Curie temperatures are obtained. Furthermore, better impedance match is reached due to the decrease of the high-frequency permittivity ε′ by about 40%–50%, which finally enhances the performance of the microwave absorption. The peak frequency (fRL) of the reflection loss (RL) curve moves toward high frequency domain and the qualified bandwidth (QB, RL ≤ ?10 dB) increases remarkably. The maximum QB of 3.3 GHz (12.0–15.3 GHz) is obtained for the Sm1.5Y0.5Fe15Si2-paraffin composite (d = 1.0 mm) and the maximum RL of ?53.6 dB is achieved for Nd2Fe15Si2-paraffin composite (d = 2.2 mm), both surpassing most of the reported MAMs. Additionally, a distinguished dielectric microwave absorption peak is observed, which further increases the QB in these composites. 相似文献